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What is this Chemistry Lab Saying?
We did a lab in class that required using copper(II) chloride dihydrate (crystals) added in water, mixed it, test the temp. and throw in a ball of aluminum foil, and test the temp. again. But for our lab the temp stayed the same throughout the entire process and the aluminum looked like it was rusting (flakes started falling off when we stirred it) with little bubbles coming out of the aluminum foil. Was the water boiling? Moreover, if it was why didn’t the temperature change at all?
I have not ever done this experiment myself – so I am working from first principles: I came across the description below of this lab. You may find it helpful. I have a problem with the chapter 4, below: The aluminium is not a catalyst in this reaction – it is a reactant. I also know that AlCl3 is not a gas. There is obviously a gas given off – you and she both report this – but I cannot identify any gas from the equation:
2Al +3 CuCl2 >> 2AlCl3 + 3 Cu
I cannot imagine that the gas is AlCl3 as the author suggests.
This is clearly an exothermic reaction, as Ms Conroy also mentions the temperature rise. I can only suggest that you did not notice this to any extent because you had a large volume of CuCl2 solution, and the mass of Al metal and CuCl2 was low. If you were to use a more concentrated solution of CuCl2 and a larger mass of Al you should get a more noticable temperature rise.
I am sorry that I cannot give a definite answer to the gas formed.
You will see that the water does not take part in the reaction.
I hope that you do this work under supervision of your teacher because exothermic reactions can be potentially dangerous.
Title – Chemical Reaction – CuCl2 + H2O + Al
By – Debbie Conroy
Primary Subject – Science
Grade Level – 5-7
What happens when aluminum foil meets a solution of copper chloride and water?
Supplies:
* glass beaker
* 100-150ml tap water
* teaspoon
* copper chloride granules
* 1 piece aluminum foil
Procedure:
1. Pour 100-150 ml of tap water in the glass, having students note the temperature of the beaker by gently touching the glass. Measure the temperature using a metal thermometer.
2. Mix 2-3 heaping teaspoons of copper chloride (CuCl2) with the water. Have the students note the color of the solution; write the chemical formula on the board or chart (CuCl2 + H2O). Ask them to feel the beaker for temperature change (an indicator that a chemical reaction is occurring) or emission of gas through bubbles (another indicator of a chemical reaction). Nothing should be happening at this point.
3. Fold a strip of aluminum foil in half and half again. Sit the foil strip in the solution. At this point do not let the kids touch the beaker or have their faces close to the beaker because the chemical reaction will happen now. Students should note that the aluminum foil portion submerged in the solution will start to change color, bubbles are occurring, a gas is being emitted and a smell is obvious. The liquid begins to change from a pretty blue to a greenish color. Using a metal spoon or other type implement submerge all of the foil into the solution as it is disintegrating.
4. Add to your chemical formula + Al which is the catalyst for the chemical reaction to occur – explain that Chlorine is an acid and is munching away at the aluminum, leaving behind just the copper portion of the copper chloride. So, in the end you have a solution of water and aluminum chloride gas, with copper being the precipitate. Spoon out the brownish material and let it dry on a paper towel – this is pure copper. The smell and gas released was the Aluminum Chloride.
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